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Table 1 Optimization of the PVC membrane composition

From: New potentiometric sensors for methylphenidate detection based on host–guest interaction

No.

Plasticizer (350 mg)

KTPB (mg)

Sensor 1

Sensor 2

Sensor 3

Slope

Range

Slope

Range

Slope

Range

1

DBS

5

50

1 × 10−3 to 1 × 10−5

45

1 × 10−3 to 1 × 10−5

47

1 × 10−3 to 1 × 10−5

2

DOP

5

59.5

1 × 10−3 to 8 × 10−6

51.5

1 × 10−3 to 8 × 10−6

56.5

1 × 10−3 to 8 × 10−6

3

o-NOPE

5

59.0

1 × 10−3 to 8 × 10−6

51.0

1 × 10−3 to 8 × 10−6

56.5

1 × 10−3 to 8 × 10−6

4

DOP

0

37

1 × 10−3 to 2 × 10−5

35

1 × 10−3 to 2 × 10−5

40

1 × 10−3 to 2 × 10−5

5

DOP

1

50

1 × 10−3 to 2 × 10−5

47

1 × 10−3 to 2 × 10−5

48

1 × 10−3 to 2 × 10−5

6

DOP

3

53

1 × 10−3 to 1 × 10−5

49

1 × 10−3 to 1 × 10−5

52.5

1 × 10−3 to 1 × 10−5

7

DOP

5

59

1 × 10−3 to 8 × 10−6

51.5

1 × 10−3 to 8 × 10−6

56.5

1 × 10−3 to 8 × 10−6

8

DOP

7

59

1 × 10−3 to 8 × 10−5

51.5

1 × 10−3 to 8 × 10−5

56.5

1 × 10−3 to 8 × 10−5

  1. Sensor 1 (β-CD), Sensor 2 (γ-CD) and Sensor 3 (calaxirene)