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Table 8 The difference of thermodynamic parameters for MZ+-phenylglycine complexes

From: Thermodynamic parameters of phenylglycine interaction with UO22+, La3+ and Zr4+

MZ+

T (°C)

Δ logK°

 − ΔΔG° (kJ/mole)

ΔΔH° (kJ/mole)

ΔΔS° (J/deg. mole)

UO22+

25

9.15

52.21

 

233.72

35

9.35

55.15

17.44

235.68

45

9.34

56.87

 

233.68

La3+

25

9.45

53.92

 

144.16

35

9.35

55.14

 − 10.96

143.44

45

9.53

56.81

 

144.18

Zr4+

25

9.16

52.32

 

233.02

35

9.06

53.43

14.14

219.39

45

9.33

56.81

 

223.11

  1. Uncertainties are [ΔG°, 0.01 kJ mol−1; ΔH°, 0.01 kJ mol−1 and ΔS°, 0.02 J/deg. mole]