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Table 4 Electronic spectral and magnetic moments of the ligand (L; PTHAC) and its metal complexes(1–3)

From: Design, spectral, molecular modeling, antimitotic, analytical and mechanism studies of phenyl isothiocyanate Girard's T derived metal complexes

Compd.

μeff (BM)

State

Absorption bands (nm)

No.

Π–π*

n–π*

d-d transitions

L

–

Nujol

240 nm, (41,667 cm−1)

272 nm, (36,765 cm−1)

292 nm, (34,246 cm−1)

341 nm, (29,326 cm−1)

–

–

(1)

2.0

Nujol

–

–

640 nm, (15,625 cm−1)

(2)

6.2

Nujol

304 nm,(32,895 cm−1)

338 nm,(29,586 cm−1)

412 nm,(24,272 cm−1)

614 nm,(16,287 cm−1)

676 nm,(14,793 cm−1)

(3)

3.9

Nujol

258 nm,(38,760 cm−1)

284 nm,(35,211 cm−1)

318 nm,(31,447 cm−1)

358 nm,(27,933 cm−1)

398 nm,(25,126 cm−1)

420 nm,(23,810 cm−1)

468 nm,(21,368 cm−1)

504 nm,(19,841 cm−1)

536 nm,(18,657 cm−1)

708 nm,(14,124 cm−1)